Reactivity parameters for nitrogen nucleophiles
Beschreibung
vor 12 Jahren
The nucleophilic reactivities of amines, hydrazines, and pyridines
were quantified using benzhydrylium ions and quinone methides as
reference electrophiles. The scope and limitations of the linear
free energy relationship log k2 = sN(N+E) for predicting rates of
the reactions of carbocations and acylation agents was studied.
were quantified using benzhydrylium ions and quinone methides as
reference electrophiles. The scope and limitations of the linear
free energy relationship log k2 = sN(N+E) for predicting rates of
the reactions of carbocations and acylation agents was studied.
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